Delrin (POM-H acetal homopolymer) and nylon (PA6/PA66 polyamide) dominate the engineering plastics category for CNC-machined components — gears, bushings, sliding mechanisms, and structural brackets. Both materials machine well, resist wear, and cost less than metals. Yet choosing the wrong one can mean dimensional drift in humid environments, premature gear failure, or machining costs that exceed the material savings.
This guide compares Delrin and nylon across mechanical properties in both dry and conditioned states, moisture-driven dimensional change, CNC cutting parameters, total cost of ownership, and chemical resistance. It concludes with a five-question framework that maps common application scenarios to the correct material.
Table of Contents
- Quick Property Comparison Table
- Moisture-Driven Property Decay: The 50% RH Reality
- Mechanical Properties Deep Dive
- CNC Cutting Parameters & Surface Finish Targets
- Chemical Resistance Head-to-Head
- Grade Selection Matrix: Which Delrin and Which Nylon
- Total Cost of Ownership: Material Price vs Part Cost
- Failure Mode Comparison: How Each Material Fails
- 5-Question Decision Framework
- Key Takeaways
Quick Property Comparison Table
The table below summarizes the most frequently referenced properties. All values represent unfilled, extruded grades tested per ASTM standards at 23°C. Where nylon properties differ between dry-as-molded (DAM) and conditioned (50% RH) states, both values appear — a distinction most comparison guides omit.
| Property | Delrin 150 (POM-H) | Nylon 66 (PA66) — Dry | Nylon 66 (PA66) — 50% RH | Test Standard |
|---|---|---|---|---|
| Tensile Strength at Yield | 76 MPa✅ | 85 MPa | 62 MPa | ASTM D638 |
| Tensile Modulus | 3.1 GPa✅ | 3.2–3.5 GPa | 2.0 GPa | ASTM D638 |
| Flexural Modulus | 2.9 GPa✅ | 3.1 GPa | 1.8 GPa | ASTM D790 |
| Elongation at Break | 25–40% | 40–70% | 150%+ | ASTM D638 |
| Density | 1.41 g/cm³✅ | 1.15 g/cm³ | 1.15 g/cm³ | ASTM D792 |
| Water Absorption (24h) | 0.25%✅ | 1.3% | ASTM D570 | |
| Melting Point | 175°C | 258°C | ASTM D3418 | |
| Continuous Service Temp | 85–100°C | 80–100°C | UL 746B | |
| Rockwell Hardness (M) | 94✅ | 100 (dry) | 75 | ASTM D785 |
| Coefficient of Friction (static) | 0.20 | 0.35 | 0.20 | ASTM D1894 |
The numbers reveal a pattern that single-state comparison tables miss: nylon’s dry-state properties often exceed Delrin’s, but those advantages erode once the material absorbs ambient moisture. In a climate-controlled electronics enclosure, nylon performs well. In an outdoor hydraulic system exposed to 60–80% RH, Delrin’s property consistency becomes the decisive advantage.
Moisture-Driven Property Decay: The 50% RH Reality
Moisture absorption is the single most important differentiator between these two materials, yet most comparison guides treat it as a line item rather than the system-level concern it represents. Nylon is hygroscopic by molecular design — the amide groups (-CONH-) in its polymer backbone form hydrogen bonds with water. Delrin’s polyoxymethylene backbone contains no such sites, making it essentially non-hygroscopic.
Moisture Absorption Rates by Environment
| Condition | Delrin (POM-H) | PA6 | PA66 | PA612 |
|---|---|---|---|---|
| 24h Immersion (ASTM D570) | 0.25% | 1.6% | 1.3% | 0.3% |
| 50% RH Equilibrium (indoor) | 0.2% | 2.6% | 2.5% | 0.7% |
| 100% RH Saturation | 0.9% | 9.5% | 8.5% | 2.5% |
What Moisture Does to Nylon’s Mechanical Properties
Absorbed water acts as a plasticizer in nylon. It pushes polymer chains apart, increases molecular mobility, and reduces glass transition temperature. The practical effect on CNC-machined parts is significant:
| Property | PA66 Dry | PA66 at 50% RH | Change |
|---|---|---|---|
| Tensile Modulus | 3.2 GPa | 2.0 GPa | −37% |
| Tensile Strength | 85 MPa | 62 MPa | −27% |
| Yield Strength | 75 MPa | 55 MPa | −27% |
| Impact Strength (Izod) | 50 J/m | 150–200 J/m | +200–300% |
| Hardness (Rockwell M) | 100 | 75 | −25% |
This dimensional instability is why KUSLA Prototype routinely recommends Delrin over nylon for any precision component that operates in uncontrolled humidity — CNC machining tight-tolerance features into a material that will drift defeats the purpose of precision manufacturing.
Mechanical Properties Deep Dive
Strength and Stiffness
In dry-as-molded condition, nylon 66 holds an edge in tensile strength (85 MPa vs 76 MPa) and tensile modulus (3.2–3.5 GPa vs 3.1 GPa). This advantage disappears at 50% RH, where nylon’s modulus drops to 2.0 GPa — 35% below Delrin’s stable 3.1 GPa. For parts that must maintain stiffness in service rather than on the datasheet, Delrin is the safer specification.
Impact Resistance and Toughness
Nylon’s moisture absorption, while detrimental to stiffness, dramatically improves impact resistance. Conditioned PA66 absorbs 150–200 J/m in notched Izod testing — three to four times its dry-state value and roughly double Delrin’s 60–80 J/m. Applications subject to repeated shock loading or accidental impact (protective housings, snap-fit brackets, cable guides) favor nylon for this reason.
Wear and Friction
Delrin exhibits a lower and more consistent coefficient of friction: 0.20 static / 0.15 dynamic against steel, compared to nylon’s 0.35 / 0.25 in dry conditions. Nylon’s friction drops when conditioned (absorbed water acts as a lubricant), approaching 0.15–0.20, but this improvement depends on ambient humidity — an unreliable parameter for engineering design. For sliding contact surfaces, bearings, and gear teeth where friction consistency matters, Delrin is the standard choice among materials engineers (per Machinery’s Handbook recommendations for low-friction polymer applications).
Fatigue and Creep Resistance
Delrin’s crystalline structure (approximately 75% crystallinity vs nylon’s 35–45%) provides superior creep resistance under sustained loads. A Delrin spring clip retains 90%+ of its initial deflection force after 1,000 hours at 23°C and 7 MPa stress. Nylon under identical conditions loses 15–25% of initial force due to higher creep compliance — exacerbated by any moisture uptake during service.
CNC Cutting Parameters & Surface Finish Targets
Both materials machine cleanly relative to metals, but their chip formation behavior differs enough to require distinct parameter sets. Delrin produces short, brittle chips that clear easily; nylon generates longer, stringier chips that can wrap around tooling if speeds and feeds are not optimized.
| Parameter | Delrin (POM-H) | Nylon (PA6/PA66) | Notes |
|---|---|---|---|
| Cutting Speed (turning) | 200–500 m/min | 150–400 m/min | Delrin tolerates higher speeds without melting |
| Feed Rate (turning) | 0.1–0.4 mm/rev | 0.1–0.3 mm/rev | Reduce nylon feed to control chip stringing |
| Depth of Cut (roughing) | Up to 3.0 mm | Up to 2.5 mm | Nylon’s elasticity causes deflection at deeper cuts |
| Achievable Tolerance | ±0.01 mm | ±0.02–0.05 mm | Nylon’s post-machining moisture uptake widens effective tolerance |
| Surface Finish (Ra, as-machined) | 0.8–1.6 µm | 1.6–3.2 µm | Delrin achieves finer finish without secondary operations |
| Coolant Recommendation | Air blast preferred | Air blast; mist if needed | Avoid flood coolant on nylon (moisture absorption) |
| Tool Type | Uncoated carbide or HSS | Uncoated carbide, sharp edges | Polished rake faces reduce nylon adhesion |
Cycle time differences compound across production runs. Delrin’s higher allowable cutting speed and deeper cuts typically result in 15–30% shorter cycle times per part compared to nylon — a factor that directly affects machining cost per unit.
Chemical Resistance Head-to-Head
Chemical environment compatibility is frequently overlooked in Delrin-vs-nylon comparisons, despite being a deciding factor in automotive, food processing, and industrial equipment applications. Neither material is universally resistant, and their vulnerabilities are complementary — meaning the chemical environment alone can dictate the choice.
| Chemical Category | Delrin | Nylon | Winner |
|---|---|---|---|
| Dilute Acids (pH 4–6) | Good | Poor — hydrolysis risk | Delrin |
| Strong Acids (pH <3) | Poor — degrades | Poor — rapid attack | Neither |
| Strong Alkalis (pH >10) | Poor — oxidative degradation | Good | Nylon |
| Hydrocarbon Solvents | Excellent | Excellent | Tie |
| Automotive Fuels / Oils | Excellent | Good to Excellent | Slight Delrin edge |
| Hot Water (>60°C) | Good to 80°C | Fair — accelerated hydrolysis | Delrin |
| Zinc Chloride Solutions | Good | Poor — stress cracking | Delrin |
| Chlorinated Solvents | Good | Fair | Delrin |
A practical rule: Delrin fails in strong oxidizing acids and strong bases. Nylon fails in any acidic environment and in zinc chloride solutions (common in electroplating and flux residues). When the operating environment includes both acid and base exposure at different stages, consider PEEK or UHMW-PE as alternatives — KUSLA Prototype provides material selection support for these edge cases.
Grade Selection Matrix: Which Delrin and Which Nylon
Specifying “Delrin” or “nylon” on a drawing is insufficient — each family contains grades with meaningfully different properties. The table below maps common CNC machining applications to specific grades, helping engineers avoid the generic specification that leads to supplier substitutions.
| Application | Recommended Grade | Why This Grade | Avoid |
|---|---|---|---|
| Precision gears, cams | Delrin 150 (POM-H) | Lowest friction, highest dimensional stability | PA6 (moisture drift); POM-C (lower crystallinity) |
| Structural brackets under impact | PA66 (conditioned) | Impact resistance 150–200 J/m conditioned | Delrin (brittle failure at high impact rates) |
| Bearings, bushings (dry running) | Delrin AF (PTFE-filled) | CoF 0.14, self-lubricating | Standard PA66 (high friction without lubrication) |
| Bearings (lubricated systems) | PA66 + MoS₂ (Nylatron GS) | Embedded lubricant, good load capacity | Standard POM (unnecessary cost premium) |
| Food contact parts | Delrin 100 (FDA-compliant) | Low moisture absorption prevents bacterial harborage | PA6 (absorbs sugars/acids from food process fluids) |
| Chemical-exposed components | PA612 or PA12 | Best chemical resistance among nylons, low moisture | PA6 (highest moisture, lowest chemical resistance) |
| Spring clips, snap fits | Delrin 500 (high-viscosity) | Higher fatigue endurance, maintains spring force | PA66 dry (may crack); PA66 conditioned (loses force) |
| Large structural parts (>200 mm) | PA66 extruded | 22% lighter than Delrin (1.15 vs 1.41 g/cm³) | Delrin (heavier, higher material cost at large volumes) |
When drawings specify “acetal” without further qualification, most CNC suppliers will default to acetal copolymer (POM-C), which has slightly lower mechanical properties than Delrin (POM-H). For critical applications, specify the exact trade name and grade number, or reference the equivalent ISO material designation (POM-H per ISO 9988 or PA66 per ISO 1874).
Total Cost of Ownership: Material Price vs Part Cost
Raw material price comparisons consistently show nylon as the cheaper option — PA6 rod stock runs $4.50–$6.50/kg versus $7.50–$11.00/kg for Delrin homopolymer. This 40–70% material cost advantage disappears and frequently reverses when total part cost is calculated.
Cost Breakdown Model: 50 mm Precision Gear, 500-Unit Run
| Cost Component | Delrin Part | Nylon Part | Delta |
|---|---|---|---|
| Material (per part) | $5.10 | $3.20 | Nylon −$1.90 |
| Machining (cycle time) | $6.80 | $8.50 | Delrin −$1.70 |
| Scrap / rejected parts | $0.25 (2–3% rate) | $0.95 (8–15% rate) | Delrin −$0.70 |
| Secondary ops (deburr, finish) | $0.15 | $0.65 | Delrin −$0.50 |
| Total per part | $12.30 | $13.30 | Delrin −$1.00 (−7.5%) |
The cost inversion happens because Delrin’s superior machinability compounds across multiple cost drivers: faster cycle times (15–30% shorter), lower scrap rates from dimensional consistency, and fewer secondary operations due to better as-machined surface finish. For precision parts with tolerances tighter than ±0.05 mm, Delrin is almost always the lower-cost option at the part level despite the material premium.
Failure Mode Comparison: How Each Material Fails
Understanding how a material fails is as important as understanding its steady-state properties. Delrin and nylon fail through different mechanisms, and matching the dominant failure mode to the application prevents in-service surprises.
| Failure Mode | Delrin Behavior | Nylon Behavior |
|---|---|---|
| Impact overload | Brittle fracture — sudden, clean break. Minimal plastic deformation before failure. | Ductile yielding — material deforms, whitens at stress points, and absorbs energy before breaking (conditioned state). |
| Fatigue (cyclic loading) | Excellent fatigue endurance. Maintains 60–70% of static strength at 10⁷ cycles. | Good when dry; degrades when conditioned. Moisture reduces fatigue limit by ~25%. |
| Creep (sustained load) | Low creep compliance. Maintains dimensional form under sustained stress at room temperature. | Higher creep rate, especially when conditioned. Springs and clips lose force over time. |
| Thermal degradation | Decomposes to formaldehyde above 230°C. Emits hazardous fumes if overheated during machining. | Chars and melts. Higher melting point (258°C) provides a wider thermal safety margin. |
| Moisture-induced | Negligible. Dimensions stable across humidity ranges. | Swelling, softening, dimensional drift. Can cause gear binding, seal failure, interference fits. |
| UV degradation | Fair — yellows and becomes brittle after extended UV exposure without stabilizers. | Poor to Fair — also degrades under UV. Both require UV-stabilized grades for outdoor use. |
In safety-critical applications where sudden brittle fracture is unacceptable — think protective guards, structural mounts, or any part where failure must be visible before catastrophic — conditioned nylon’s ductile failure mode is the safer engineering choice. Conversely, when dimensional precision must be maintained over the part’s service life, Delrin’s stability outweighs its brittleness concern.
5-Question Decision Framework
Answer These Five Questions to Select Your Material
- Will the part operate in uncontrolled humidity (>40% RH)?
Yes → Delrin. Nylon’s property decay above 40% RH is too significant for precision applications. - Does the part require impact resistance or ductile failure behavior?
Yes → Nylon (PA66, conditioned). No → Delrin. - Is the tolerance requirement tighter than ±0.05 mm?
Yes → Delrin. Nylon cannot reliably hold sub-0.05 mm tolerances after moisture conditioning. - Is the part a sliding surface, gear, or bearing operating without external lubrication?
Yes → Delrin (or Delrin AF for extreme low-friction). Its stable CoF of 0.20 eliminates reliance on ambient moisture for lubricity. - Will the part contact strong alkalis (pH >10) or zinc chloride solutions?
Alkalis → Nylon. Zinc chloride → Delrin. Both → Consider PA612 or PEEK.
When multiple questions point to different materials, prioritize the operating environment (Question 1) and tolerance requirement (Question 3) — these two factors cause the most in-service failures. Impact and chemical resistance can often be addressed through design changes (ribbing, wall thickness) rather than material substitution.
For projects where neither Delrin nor nylon is a clear fit — high-temperature, chemically aggressive, or structurally demanding applications — consider metal alternatives or advanced polymers like PEEK. KUSLA Prototype supports material selection consultations through the engineering team.
Key Takeaways
Delrin (POM-H) is the default choice for CNC-machined precision components operating in real-world humidity conditions. Its dimensional stability, low and consistent friction, excellent fatigue resistance, and superior machinability result in lower total part cost despite a higher raw material price. Nylon (PA66) earns its place in applications requiring impact toughness, alkaline chemical resistance, or lightweight large-format parts where tight tolerances are not critical.
The most common specification error is selecting nylon for a tight-tolerance application based on its dry-state datasheet properties, then discovering dimensional drift weeks after installation. Specifying against conditioned-state properties — not dry-as-molded properties — prevents this failure mode.
Both materials machine well in the hands of an experienced CNC shop. The material choice determines the process parameters, but not the achievable quality — provided the shop understands the material’s behavior. KUSLA Prototype machines both Delrin and nylon across thousands of part geometries annually, with in-process dimensional monitoring that accounts for each material’s post-machining behavior.
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Get a Quote →Data Sources & Standards Referenced
- DuPont Delrin 150 Product Data Sheet (POM-H Homopolymer)
- Direct Plastics Nylon 66 Technical Data Sheet
- MatWeb Material Property Database — POM-H and PA66 entries
- ASTM D638 (Tensile Properties), ASTM D790 (Flexural Properties), ASTM D570 (Water Absorption)
- ASTM D785 (Rockwell Hardness), ASTM D256 (Izod Impact)
- ISO 9988 (POM designation), ISO 1874 (PA designation)
- Machinery’s Handbook, 31st Edition — Polymer friction and wear data